It is the agricultural sector that currently produces the largest share of biomass crops, such as corn for ethanol and soybeans for biodiesel, as well as new crops in use or evaluation as sources of biomass energy and bioproducts. The last agricultural census (USDA-ERS, 2002) showed the total U.S. cropland at 442 million acres. Cropland use is typically dynamic, due to annual crop and land rotations to conserve soil fertility, and the need to shift land use in response to market trends. The 2002 census reported 340 million acres as cropland used for crops (as opposed to cropland pasture being grazed in rotation [62 million acres]), and idle cropland (40 million acres). Of the idle cropland acres, 35 million acres were enrolled under the expanding Federal Conservation Reserve Program or CRP (figure 2). Harvesting of biomass is permitted by the CRP under certain conditions.

The major crops produced on U.S. cropland in 2002 were corn (69 million acres), soybeans (72.5 million acres), wheat (50 million acres), alfalfa (22 million acres), other hay (38 million acres), and cotton (13 million acres). The remaining crop acres were in miscellaneous grain and oil seed crops, and fruits and vegetables.
At present, corn, soybeans, alfalfa and other hay are produced primarily for livestock feed. A significant and increasing portion of corn production is currently used to produce bioenergy and bioproducts. In 2005, about 2.15 billion bushels of corn were used to produce 3.9 billion gallons of fuel ethanol. Corn is also used to produce bioproducts, such as polylactic acid (biodegradable plastic) and 1,3-propanediol, used to produce Sorona®, a synthetic fabric. Soybean oil goes mainly to food uses; however, industrial uses include soybean oil used to produce biodiesel - 30 million gallons in 2004, using about 20 million of the U.S. total 1.65 billion soybean bushel production. About 4% of the soybean oil produced in 2004 was used to produce bioproducts such as inks, adhesives and binders, plastics and detergents, among others.